68247 Diethyl L-(+)-tartrate - AK Scientific
 
 
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  Catalog ID # 68247
Diethyl L-(+)-tartrate
, 99%
 
L(+)-Diethyl L-tartrate
L-(+)-Tartaric acid diethyl ester




IDENTITY
CAS Registry #:[87-91-2]
MDL Number:MFCD00009143
MF:C8H14O6
MW:206.1932
EINECS:201-783-3
BRN:1727145
SPECIFICATIONS & PROPERTIES
Purity:99%
Concentration:e.e. 99%
Physical Form:Colorless to light yellow clear viscous liquid
Melting Point:17°C
Boiling Point:280°C
Flash Point:93°C
Optical Rotation:+7.6°-+8.5°, neat
Density:1.204-1.205
Refractive Index:1.445-1.447
Shipping:Normal Temperature

REFERENCES
[1]Chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols through asymmetric Simmons-Smith reaction: Chem. Lett., 61 (1992).
[2] Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols: J. Am. Chem. Soc., 102, 5974 (1980).
[3] Enantioselective oxidation of sulfides to sulfoxides: Org. Synth. Coll., 8, 464 (1993).
[4] Review on tartrate esters as chiral auxiliaries, such as Simmons-Smith reaction and in 1,3-dipolar cycloaddition reactions: Synlett, 1075 (2003).

Risk Description(s)
R36/37/38:Irritating to eyes, respiratory system and skin

Safety Description(s)
S15:Keep away from heat.
S24/25:Avoid contact with skin and eyes.


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RELATED PRODUCTS
68247Diethyl L-(+)-tartrate
68250(-)-Diethyl D-tartrate

CATEGORIES

 Chiral Synthesis > Tartaric Acids

USEFUL LINKS

  @PubChem