68247 Diethyl L-(+)-tartrate - AK Scientific
 
 
Loading Please Wait...
  Catalog ID # 68247
Diethyl L-(+)-tartrate
, 99%
 
L(+)-Diethyl L-tartrate
L-(+)-Tartaric acid diethyl ester




IDENTITY
CAS Registry #:[87-91-2]
MDL Number:MFCD00009143
MF:C8H14O6
MW:206.19
EINECS:201-783-3
BRN:1727145
SPECIFICATIONS & PROPERTIES
Purity:99%
Concentration:e.e. 99%
Physical Form:Colorless to light yellow clear viscous liquid
Melting Point:17°C
Boiling Point:280°C
Flash Point:93°C
Optical Rotation:+7.6°-+8.5°, neat
Density:1.204-1.205
Refractive Index:1.445-1.447
Shipping:Not Regulated for Shipping.

REFERENCES
[1]Chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols through asymmetric Simmons-Smith reaction: Chem. Lett., 61 (1992).
[2] Chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols: J. Am. Chem. Soc., 102, 5974 (1980).
[3] Enantioselective oxidation of sulfides to sulfoxides: Org. Synth. Coll., 8, 464 (1993).
[4] Review on tartrate esters as chiral auxiliaries, such as Simmons-Smith reaction and in 1,3-dipolar cycloaddition reactions: Synlett, 1075 (2003).

Risk Description(s)
R36/37/38:Irritating to eyes, respiratory system and skin

Safety Description(s)
S15:Keep away from heat.
S24/25:Avoid contact with skin and eyes.


Pricing (not showing? please refresh your web browser)

RELATED PRODUCTS
68247Diethyl L-(+)-tartrate
68250(-)-Diethyl D-tartrate

CURRENT AS OF: March 6, 2015
Availability
1. In Stock: Order today by 4 PM PT and ships today from San Francisco, CA, USA
2. Backordered: Please contact us for availability.
3. If Bulk (kg) is Backordered, sizes less than 1kg may be available.
4. All prices FOB San Francisco, CA, USA
HazMat
HazMat shipping information is based on IATA/DOT regulations. For reference only.
1. None: Not regulated by IATA/DOT. Normal shipping for Ground and Express.
2. For Express Shipping Only: HazMat shipping for Express. Normal shipping for domestic Ground.

SDS

 68247_SDS.pdf

CATEGORIES

 Chiral Synthesis > Tartaric Acids

USEFUL LINKS

  PubChem